Cr3+掺杂的宽带近红外荧光粉及其研究进展

张亮亮; 张家骅; 郝振东; 吴昊; 潘国徽; 武华君; 张霞

doi:10.3788/fgxb20194012.1449

您当前的位置：

首页 >

文章列表页 >

Cr³⁺掺杂的宽带近红外荧光粉及其研究进展

特邀报告 | 更新时间：2020-08-12

- Cr³⁺掺杂的宽带近红外荧光粉及其研究进展
- Recent Progress on Cr³⁺ Doped Broad Band NIR Phosphors
- 发光学报 2019年40卷第12期页码：1449-1459
- 作者机构：
  
  中国科学院长春光学精密机械与物理研究所发光学及应用国家重点实验室,吉林长春,130033
- 作者简介：
- 基金信息：
  
  国家重点研发计划（2016YFB0400605，2016YFB0701003，2017YFB0403104）();国家自然科学基金（11874055，51772286，
- DOI：10.3788/fgxb20194012.1449
  中图分类号： O482.31;TH691.9;TP391.4
- 纸质出版日期：2019-12-5，
  
  网络出版日期：2019-12-5，
  
  收稿日期：2019-11-23，
  
  修回日期：2019-12-5，
扫描看全文
张亮亮, 张家骅, 郝振东等. Cr3+掺杂的宽带近红外荧光粉及其研究进展[J]. 发光学报, 2019,40(12): 1449-1459

ZHANG Liang-liang, ZHANG Jia-hua, HAO Zhen-dong etc. Recent Progress on Cr3+ Doped Broad Band NIR Phosphors[J]. Chinese Journal of Luminescence, 2019,40(12): 1449-1459
张亮亮, 张家骅, 郝振东等. Cr3+掺杂的宽带近红外荧光粉及其研究进展[J]. 发光学报, 2019,40(12): 1449-1459 DOI： 10.3788/fgxb20194012.1449.

ZHANG Liang-liang, ZHANG Jia-hua, HAO Zhen-dong etc. Recent Progress on Cr3+ Doped Broad Band NIR Phosphors[J]. Chinese Journal of Luminescence, 2019,40(12): 1449-1459 DOI： 10.3788/fgxb20194012.1449.

摘要

具有非损伤、快速检测特点的近红外光谱技术与近红外成像技术在食品成分检测、癌症早期诊断、脑科学等领域获得了越来越多应用，其面临的技术瓶颈之一就是缺乏一种具有小型化、快速响应特点的宽带近红外光源。为解决该问题，荧光粉转化的宽带近红外LED（pc-LED）逐渐在众多技术方案中脱颖而出。本综述重点总结了宽带近红外pc-LED核心材料Cr

掺杂的宽带近红外荧光粉的研究进展，并详细介绍了宽带近红外光源的应用背景及光源种类，总结了Cr

的发光特性。本综述针对Cr

掺杂的宽带近红外荧光粉需要解决的重要问题展开讨论，包含了效率提升、发射谱带展宽、电声耦合问题和应用探索四个方面，以帮助读者了解该研究课题的现状、面临问题及未来发展趋势。

Abstract

Near infrared spectroscopy and imaging technology had been applied in fields such as food analysis

early diagnosis of cancer

and brain science. However

this technology was still suffered from lacking of broad band near infrared (NIR) light source. To solve the problem

phosphor converted broad band NIR LED (pc-LED) developed into a promising solution. This review summarized recent progress on the decisive material of NIR pc-LED:Cr

doped broad band NIR phosphors. Applications that demanding broad band NIR source

technology of current broad band NIR source

and luminescence property of Cr

were introduced. Some important topics for Cr

doped broad band NIR phosphors

such as efficiency

band width

electron-phonon coupling

and application

were also discussed. This review will help readers to understand recent progress

problems

and future of Cr

doped broad band NIR phosphors.

关键词

LED近红外荧光粉铬宽带

Keywords

LEDnear infrared lightphosphorCr3+broad band

references

EGGEBRECHT A T,FERRADAL S L,ROBICHAUX-VIEHOEVER A,et al.. Mapping distributed brain function and networks with diffuse optical tomography[J]. Nat. Photon., 2014,8(6):448-454.

ZENG B B,HUANG Z Q,SINGH A,et al.. Hybrid graphene metasurfaces for high-speed mid-infrared light modulation and single-pixel imaging[J]. Light Sci. Appl., 2018,7(1):51.

XIAO Y Z,CHARIPAR N A,SALMAN J,et al.. Nanosecond mid-infrared pulse generation via modulated thermal emissivity[J]. Light Sci. Appl., 2019,8(1):51.

HOVING-BOLINK A H,VEDDER H W,MERKS J W M,et al.. Perspective of NIRS measurements early post mortem for prediction of pork quality[J]. Meat Sci., 2005,69(3):417-423.

VENTURA M,DE JAGER A,DE PUTTER H,et al.. Non-destructive determination of soluble solids in apple fruit by near infrared spectroscopy (NIRS)[J]. Postharvest Biol. Technol., 1998,14(1):21-27.

QIAO J W,ZHOU G J,ZHOU Y Y,et al.. Divalent europium-doped near-infrared-emitting phosphor for light-emitting diodes[J]. Nat. Commun., 2019,10(1):5267-1-7.

ZHAO M,LIAO H X,MOLOKEEV M,et al.. Emerging ultra-narrow-band cyan-emitting phosphor for white LEDs with enhanced color rendition[J]. Light Sci. Appl., 2019,8(1):38-1-9.

PULLI T,DNSBERG T,POIKONEN T,et al.. Advantages of white LED lamps and new detector technology in photometry[J]. Light Sci. Appl., 2015,4:e332-1-21.

RAJENDRAN V,CHANG H,LIU R S. (INVITED) Recent progress on broadband near-infrared phosphors-converted light emitting diodes for future miniature spectrometers[J]. Opt. Mater.:X, 2019,1:100011-1-11.

FUCHI S,SAKANO A,TAKEDA Y.Wideband infrared emission from Yb3+ and Nd3+-doped Bi2O3-B2O3 glass phosphor for an optical coherence tomography light source[J]. Jpn. J. Appl. Phys., 2008,47(10R):7932-7935.

FUCHI S,SAKANO A,MIZUTANI R,et al.. High power and high resolution near-infrared light source for optical coherence tomography using glass phosphor and light emitting diode[J]. Appl. Phys. Express, 2009,2(3):032102.

UEMURA H,FUCHI S,KATO R,et al.. Development of near-infrared absorption spectrometry system by using NIR wideband glass phosphor LED[J]. J. Phys.:Conf. Ser., 2015,619(1):012053-1-4.

NISHIMURA S,FUCHI S,TAKEDA Y. Luminescence properties of Tm2O3-doped oxide glasses for NIR wideband light source[J]. J. Mater. Sci.:Mater. Electron., 2017,28(10):7157-7162.

SHAO Q Y,DING H,YAO L Q,et al.. Photoluminescence properties of a ScBO3:Cr3+ phosphor and its applications for broadband near-infrared LEDs[J]. RSC Adv., 2018,8(22):12035-12042.

SHAO Q Y,DING H,YAO L Q,et al.. Broadband near-infrared light source derived from Cr3+-doped phosphors and a blue LED chip[J]. Opt. Lett., 2018,43(21):5251-5254.

RAJENDRAN V,FANG M H,DE GUZMAN G N,et al.. Super broadband near-infrared phosphors with high radiant flux as future light sources for spectroscopy applications[J]. ACS Energy Lett., 2018,3(11):2679-2684.

ZHANG L L,ZHANG S,HAO Z D,et al.. A high efficiency broad-band near-infrared Ca2LuZr2Al3O12:Cr3+ garnet phosphor for blue LED chips[J]. J. Mater. Chem. C, 2018,6(18):4967-4976.

ZHANG L L,WANG D D,HAO Z D,et al.. Cr3+-doped broadband NIR garnet phosphor with enhanced luminescence and its application in NIR spectroscopy[J]. Adv. Opt. Mater., 2019,7(12):1900185.

程丽娟,刘贵珊,万国玲,等. 可见/近红外高光谱成像技术对长枣中葡萄糖含量的无损检测[J].发光学报,2019,40(8):1055-1063. CHENG L J,LIU G S,WAN G L,et al.. Non-destructive detective of glucose contect in Lingwu jujube by Vis/NIR hyperspectral imaging technology[J]. Chin. J. Lumin., 2019,40(8):1055-1063. (in Chinese)

丁佳兴,杨晓玉,房盟盟,等.可见/近红外高光谱成像技术对鸡蛋种类无损判别[J].发光学报, 2018,39(3):394-402. DING J X,YANG X Y,FANG M M,et al.. Non-destructive discrimination of different kinds egg by Vis/NIR hyperspectral imaging technique[J]. Chin. J. Lumin., 2018,39(3):394-402. (in Chinese)

NORRIS K H. Design and development of a new moisture meter[J]. Agric. Eng., 1964,45(7):370-372.

NICOLA B M,BEULLENS K,BOBELYN E,et al.. Nondestructive measurement of fruit and vegetable quality by means of NIR spectroscopy:a review[J]. Postharvest Biol. Technol., 2007,46(2):99-118.

JBSIS F F. Noninvasive,infrared monitoring of cerebral and myocardial oxygen sufficiency and circulatory parameters[J]. Science, 1977,198(4323):1264-1267.

FERRARI M,QUARESIMA V. A brief review on the history of human functional near-infrared spectroscopy (fNIRS) development and fields of application[J]. NeuroImage, 2012,63(2):921-935.

FUCHI S,TAKEDA Y. Wideband near-infrared phosphor by stacking Sm3+ doped glass underneath Yb3+,Nd3+ co-doped glass[J]. Phys. Status Solidi C, 2011,8(9):2653-2656.

CHEN C,SONG W G,CHEN J W,et al.. Spectral tomographic imaging with aplanatic metalens[J]. Light Sci. Appl., 2019,8(1):99.

ZHANG P F,LI L,LIN L,et al.. In vivo superresolution photoacoustic computed tomography by localization of single dyed droplets[J]. Light Sci. Appl., 2019,8(1):36-1-9.

JOSIS F F. Discovery of the near-infrared window into the body and the early development of near-infrared spectroscopy[J]. J. Biomed. Opt., 1999,4(4):392-396.

AZIZ N A M,ARSAD N,MENON P S,et al.. An assessment study of absorption effect:LED vs tungsten halogen lamp for noninvasive glucose detection[J]. J. Innov. Opt. Health Sci., 2015,8(2):1550013-1-5.

LUKOVIC M,LUKOVIC V,BELCA I,et al.. LED-based Vis-NIR spectrally tunable light source-the optimization algorithm[J]. J. Eur. Opt. Soc., 2016,12:19-1-12.

LY K T,CHEN-CHENG R W,LIN H,et al.. Near-infrared organic light-emitting diodes with very high external quantum efficiency and radiance[J]. Nat. Photon., 2017,11(1):63-68.

REID B L,STAGNI S,MALICKA J M,et al.. Lanthanoid -triketonates:a new class of highly efficient NIR emitters for bright NIR-OLEDs[J]. Chem. Commun., 2014,50(78):11580-11582.

YAMANAKA T,NAKANOTANI H,HARA S,et al.. Near-infrared organic light-emitting diodes for biosensing with high operating stability[J]. Appl. Phys. Express, 2017,10(7):074101.

吴梅虹,罗岚,郭锐,等.新型Ba3SiO5:Eu荧光粉的合成及光谱性质[J].发光学报, 2019,40(5):610-615. WU M H,LUO L,GUO R,et al.. Synthesis and photoluminescent properties of Ba3SiO5:Eu phosphor[J]. Chin. J. Lumin., 2019,40(5):610-615. (in Chinese)

金叶,陈远豪,刘浩文,等. 红色荧光粉Na8.33La1.67(SiO4)6O2:Eu3+的制备及发光特性[J]. 发光学报, 2019,40(2):159-163. JIN Y,CHEN Y H,LIU H W,et al.. Synthesis and luminescence properties of red phosphor Na8.33La1.67(SiO4)6O2:Eu3+[J]. Chin. J. Lumin., 2019,40(2):159-163. (in Chinese)

符义兵,何锦华,梁超,等. 全光谱照明LED中的蓝绿色荧光粉研究[J].发光学报,2018,39(9):1220-1224. FU Y B,HE J H,LIANG C,et al.. Blue-green phosphors in full spectrum lighting LEDs[J]. Chin. J. Lumin., 2018,39(9):1220-1224. (in Chinese)

LEVER A B P. The crystal field splitting parameter Dq:calculation and significance[M]. Kauffman G B. Werner Centennial. Washington D.C.:American Chemical Society, 1967.

STRUVE B,HUBER G. The effect of the crystal field strength on the optical spectra of Cr3+ in gallium garnet laser crystals[J]. Appl. Phys. B, 1985,36(4):195-201.

MALYSA B,MEIJERINK A,WU W W,et al.. On the influence of calcium substitution to the optical properties of Cr3+ doped SrSc2O4[J]. J. Lumin., 2017, 190:234-241.

HAM F S. The Jahn-Teller effect:a retrospective view[J]. J. Lumin., 2000,85(4):193-197.

MCCUMBER D E. Effect of lattice dynamics on optical properties[J]. J. Lumin., 2000,85(4):171-175.

GRINBERG M,JASKOLSKI W,MACFARLANE P I,et al.. Crystal field distribution and non-radiative transitions in Cr3+ -doped gallogermanates[J]. J. Lumin., 1997,72-74:193-194.

黄昆. 晶格弛豫和多声子跃迁理论[J].物理学进展, 1981,1(1):31-85. HUANG K. Lattice relaxation and theory of multiphonon transitions[J]. Prog. Phys., 1981,1(1):31-85. (in Chinese)

GRINBERG M,MACFARLANE P I,HENDERSON B,et al.. Inhomogeneous broadening of optical transitions dominated by low-symmetry crystal-field components in Cr3+-doped gallogermanates[J]. Phys. Rev. B, 1995,52(6):3917-3929.

GRINBERG M,SUCHOCKI A. Pressure-induced changes in the energetic structure of the 3d3 ions in solid matrices[J]. J. Lumin., 2007,125(1-2):97-103.

PAYNE S A,CHASE L L,WILKE G D. Optical spectroscopy of the new laser materials,LiSrAlF6:Cr3+ and LiCaAlF6:Cr3+[J]. J. Lumin., 1989,44(3):167-176.

XU X X,SHAO Q Y,YAO L Q,et al.. Highly efficient and thermally stable Cr3+-activated silicate phosphors for broadband near-infrared LED applications[J]. Chem. Eng. J., 2019:doi:10.1016/j.cej.2019.123108.

YU D C,ZHOU Y S,MA C S,et al.. Non-rare-earth Na3AlF6:Cr3+ phosphors for far-red light-emitting diodes[J]. ACS Appl. Electron. Mater., 2019,1(11):2325-2333.

YAO L Q,SHAO Q Y,XU X X,et al.. Broadband emission of single-phase Ca3Sc2Si3O12:Cr3+/Ln3+ (Ln=Nd,Yb,Ce) phosphors for novel solid-state light sources with visible to near-infrared light output[J]. Ceram. Int., 2019,45(11):14249-14255.

GAO T Y,ZHUANG W D,LIU R H,et al.. Site occupancy and enhanced luminescence of broadband NIR gallogermanate phosphors by energy transfer[J]. J. Am. Ceram. Soc., 2020,103(1):202-213.

ZENG H T,ZHOU T L,WANG L,et al.. Two-site occupation for exploring ultra-broadband near-infrared phosphor-double-perovskite La2MgZrO6:Cr3+[J]. Chem. Mater., 2019,31(14):5245-5253.

DAI D J,WANG Z J,XING Z H,et al.. Broad band emission near-infrared material Mg3Ga2GeO8:Cr3+:substitution of Ga-In,structural modification,luminescence property and application for high efficiency LED[J]. J. Alloys Compd., 2019,806:626-938.

LIN X H,ZHANG R L,TIAN X M,et al.. Coordination geometry-dependent multi-band emission and atypically deep-trap-dominated NIR persistent luminescence from chromium-doped aluminates[J]. Adv. Opt. Mater., 2018,6(7):1701161.

VINK A P,MEIJERINK A. Electron-phonon coupling of Cr3+ doped garnets[J]. J. Phys. Chem. Solids, 2000,61(10):1717-1725.

MALYSA B,MEIJERINK A,JSTEL T. Temperature dependent photoluminescence of Cr3+ doped Sr8MgLa(PO4)7[J]. Opt. Mater., 2018,85:341-348.

MALYSA B,MEIJERINK A,JSTEL T. Temperature dependent Cr3+ photoluminescence in garnets of the type X3Sc2Ga3O12 (X=Lu,Y,Gd,La)[J]. J. Lumin., 2018,202:523-531.

WANG C P,WANG X M,ZHOU Y,et al.. An ultra-broadband near-infrared Cr3+-activated gallogermanate Mg3Ga2GeO8 phosphor as light sources for food analysis[J]. ACS Appl. Electron. Mater., 2019,1(6):1046-1053.

浏览量

871

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

亚微米级Ca_2.40Lu_0.54ScMgSi₃O₁₂：0.06Ce³⁺荧光粉的溶胶燃烧法合成与表征

传统白光LED与远程荧光粉白光LED的发光性能比较

LED用绿色荧光粉BaSi₂N₂O₂:Eu²⁺的发光和封装性能

Eu²⁺ 激活的Ba_5-xSr_x(PO₄)₃Cl 的发光性质

SrIn₂O₄∶Sm³⁺红色荧光粉的发光特性