Ce<sup>3+</sup>和Eu<sup>2+</sup>掺杂荧光材料的光猝灭机理研究进展

郑鹏; 丁国真; 解荣军

doi:10.37188/CJL.20210173

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Ce³⁺和Eu²⁺掺杂荧光材料的光猝灭机理研究进展

特邀报告 | 更新时间：2021-10-17

- Ce³⁺和Eu²⁺掺杂荧光材料的光猝灭机理研究进展
  增强出版
- Research Progress on Optical Quenching of Ce³⁺- and Eu²⁺-doped Luminescent Materials
- 发光学报 2021年42卷第10期页码：1447-1457
- 作者机构：
  
  厦门大学　材料学院，福建　厦门　 361005
- 作者简介：
  
  [ "郑鹏(1991-)，男，安徽亳州人，博士研究生，2014年于北京科技大学获得硕士学位，主要从事激光照明与显示用荧光材料的研究。E-mail: zheng_peng@foxmail.com" ]
  [ "解荣军(1969-)，男，江苏镇江人，博士，教授，1998年于中国科学院上海硅酸盐研究所获得博士学位，主要从事稀土发光材料、量子点和发光器件的研究。E-mail: rjxie@xmu.edu.cn" ]
- 基金信息：
  
  国家重点研发计划(2017YFB04043);国家自然科学基金(51802274;51572232)
- DOI：10.37188/CJL.20210173
  中图分类号： O482.31
- 纸质出版日期：2021-10-01，
  
  收稿日期：2021-05-03，
  
  修回日期：2021-05-15，
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郑鹏, 丁国真, 解荣军. Ce³⁺和Eu²⁺掺杂荧光材料的光猝灭机理研究进展[J]. 发光学报, 2021,42(10):1447-1457.

Peng ZHENG, Guo-zhen DING, Rong-jun XIE. Research Progress on Optical Quenching of Ce³⁺- and Eu²⁺-doped Luminescent Materials[J]. Chinese Journal of Luminescence, 2021,42(10):1447-1457.
郑鹏, 丁国真, 解荣军. Ce³⁺和Eu²⁺掺杂荧光材料的光猝灭机理研究进展[J]. 发光学报, 2021,42(10):1447-1457. DOI： 10.37188/CJL.20210173.

Peng ZHENG, Guo-zhen DING, Rong-jun XIE. Research Progress on Optical Quenching of Ce³⁺- and Eu²⁺-doped Luminescent Materials[J]. Chinese Journal of Luminescence, 2021,42(10):1447-1457. DOI： 10.37188/CJL.20210173.

摘要

和Eu

掺杂荧光材料具有吸收率高、发射宽、荧光寿命短、光谱可调等优点，是激光照明与显示应用的理想荧光材料。然而，Ce

和Eu

掺杂荧光材料在激光激发下的发光猝灭严重限制了激光荧光光源的光效和光亮度。传统观点认为发光猝灭主要由热猝灭效应引起，然而近些年的研究结果显示，即使热猝灭效应被有效控制，高强度的激发光本身也会导致荧光材料发射效率显著下降，这种非热效应的发光猝灭可以被简称为光猝灭。本文简要概述了目前已知的四种光猝灭效应，即基态耗尽、激发态吸收、能量传递上转换和光释光效应的研究进展，并对光猝灭的未来研究方向进行了展望。

Abstract

- and Eu

-doped luminescent materials featuring high absorbance

broad emission band

short decay time

and tunable emission spectra

are ideal candidates for laser lighting and display applications. However

luminescence quenching of Ce

- and Eu

-doped luminescent materials under laser excitation severely restricts the luminous efficacy and luminance of laser-driven lighting devices. As a rule of thumb

the luminescence quenching is attributed to thermal quenching. However

recent studies have found that even if the thermal quenching is controlled

the high-intensity excitation light itself can lead to a significant decrease in the luminous efficiency of luminescent materials. This non-thermal luminescence quenching effect can be referred to as optical quenching. This article briefly reviews the latest research progress of four known optical quenching effects

namely

ground-state depletion

excited-state absorption

energy-transfer upconversion

and optically stimulated luminescence

and the prospects of studies on optical quenching are outlined.

关键词

激光照明与显示荧光材料光猝灭光饱和

Keywords

laser lighting and displayluminescent materialsoptical quenchingoptical saturation

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荧光粉中激活剂离子掺杂格位分析

Ce3+和Eu2+掺杂荧光材料的光猝灭机理研究进展

Research Progress on Optical Quenching of Ce3+- and Eu2+-doped Luminescent Materials

DOI：10.37188/CJL.20210173

摘要

Abstract

关键词

Keywords

references

Ce³⁺和Eu²⁺掺杂荧光材料的光猝灭机理研究进展

Research Progress on Optical Quenching of Ce³⁺- and Eu²⁺-doped Luminescent Materials